Evaluation of temporal trends and correlations of physical-chemical parameters in vast oceanic areas robust to information uncertainty

Chemosphere. 2023 Feb:314:137597. doi: 10.1016/j.chemosphere.2022.137597. Epub 2022 Dec 22.

Abstract

The physical-chemical monitoring of vast oceanic areas aims at assessing the status and evolution of the environmental resource for its exploration, protection and/or better understanding. However, the interpretation of monitoring data is affected by ocean seasonality and heterogeneity, and by the quality of sampling and characterization tools used to study the environment. All these factors contribute to the uncertainty of collected information that should be expressed in determined parameter values or trends. A trend of a studied parameter quantified by values difference is significant if the observed absolute value of the difference is larger than their expanded uncertainty. The correlation of studied parameters, useful for their interpretation, is equality affected by the mentioned sources of uncertainty. This work describes the metrologically sound evaluation of trends and correlations of physicochemical parameters of vast oceanic areas where all uncertainty sources affecting the information are considered by simulating their complex impact by the Monte Carlo Method. The described methodology was successfully used to study the impact of summer upwelling in an 800 km2 coastal area offshore two large cities in Portugal. Nutrients, conductivity, salinity and temperature trends and correlations are distinguished from system heterogeneity, sampling and sample analysis uncertainty for a 99% confidence level.

Keywords: Atlantic ocean; Composition trends; Compositional correlation; Information uncertainty; Nutrients; Salinity; Temperature; Upwelling.

MeSH terms

  • Environmental Monitoring* / methods
  • Monte Carlo Method
  • Nutrients*
  • Oceans and Seas
  • Seasons
  • Uncertainty