Template-Free Synthesis of Magnetic La-Mn-Fe Tri-Metal Oxide Nanofibers for Efficient Fluoride Remediation: Kinetics, Isotherms, Thermodynamics and Reusability

Shaoju Jian; Yuhuang Chen; Fengshuo Shi; Yifei Liu; Wenlong Jiang; Jiapeng Hu; Xiaoshuai Han; Shaohua Jiang; Weisen Yang

doi:10.3390/polym14245417

Template-Free Synthesis of Magnetic La-Mn-Fe Tri-Metal Oxide Nanofibers for Efficient Fluoride Remediation: Kinetics, Isotherms, Thermodynamics and Reusability

Polymers (Basel). 2022 Dec 11;14(24):5417. doi: 10.3390/polym14245417.

Authors

Shaoju Jian¹, Yuhuang Chen¹, Fengshuo Shi¹, Yifei Liu¹, Wenlong Jiang¹, Jiapeng Hu¹, Xiaoshuai Han^{1

2}, Shaohua Jiang^{1

2}, Weisen Yang¹

Affiliations

¹ Fujian Key Laboratory of Eco-Industrial Green Technology, Key Laboratory of Green Chemical Technology of Fujian Province University, College of Ecology and Resources Engineering, Wuyi University, Wuyishan 354300, China.
² Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China.

Abstract

The occurrence of fluoride contamination in drinking water has gained substantial concern owing to its serious threat to human health. Traditional adsorbents have shortcomings such as low adsorption capacity and poor selectivity, so it is urgent to develop new adsorbents with high adsorption capacity, renewable and no secondary pollution. In this work, magnetic electrospun La-Mn-Fe tri-metal oxide nanofibers (LMF NFs) for fluoride recovery were developed via electrospinning and heat treatment, and its defluoridation property was evaluated in batch trials. Modern analytical tools (SEM, BET, XRD, FTIR) were adopted to characterize the properties of the optimized adsorbent, i.e., LMF11 NFs with a La:Mn molar ratio of 1:1. The surface area calculated via BET method and pH_pzc assessed using pH drift method of LMF11 NFs were 55.81 m² g^-1 and 6.47, respectively. The results indicated that the adsorption amount was highly dependent on the pH of the solution, and reached the highest value at pH = 3. The kinetic behavior of defluoridation on LMF11 NFs was dominated by the PSO model with the highest fitted determination coefficients of 0.9999. Compared with the other three isotherm models, the Langmuir model described defluoridation characteristics well with larger correlation coefficients of 0.9997, 0.9990, 0.9987 and 0.9976 at 15 °C, 25 °C, 35 °C and 45 °C, respectively. The optimized LMF11 NFs exhibited superior monolayer defluoridation capacities for 173.30-199.60 mg F^-/g at pH 3 at 15-45 °C according to the Langmuir isotherm model. A thermodynamic study proved that the defluoridation by LMF11 NFs is a spontaneous, endothermic along with entropy increase process. In addition, the LMF11 NFs still showed high defluoridation performance after three reused cycles. These findings unveil that the synthesized LMF11 NFs adsorbent is a good adsorbent for fluoride remediation from wastewater owing to its low cost, high defluoridation performance and easy operation.

Keywords: La-Mn-Fe tri-metal oxides nanofibers; defluoridation; electrospinning; kinetics; wastewater treatment.

Abstract

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