Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes

Abstract

A new configuration of aluminum electrodes has been performed in an electrocoagulation reactor (ECR) to remove toxic metals from synthetic wastewater. The ECR contains four concentric-cubic electrodes that were connected to the DC power supply with a bipolar mode. The ability of this reactor to eliminate 200 ppm Pb, 200 ppm Cd and 200 ppm Cu from wastewater was investigated under the effect of pH (4-10), applied current (0.2-2.6 A), and the reaction time of (4-60 min). Two grams of NaCl were added to each experiment to enhance the electrical conductivity and minimize the passivation of cathode surfaces. The experiments, analysis, and optimization were conducted using response surface methodology type Box-Behnken design (RSM-BBD) and the Minitab-statistical software program. The highest elimination of heavy metals was: Pb-99.73%, Cd-98.54%, and Cu-98.92% at pH 10, 1.4 A of the applied current, and 60 min of the reaction time. The total real consumption of anodes under these conditions was 0.55 g, and the energy consumption was 12.71 kWh/m3. All reactions of metal removal that occurred in the present EC reactor obey the kinetic of a first-order reaction. Thermodynamics parameters of present electrocoagulation removal of heavy metals indicate an endothermic, spontaneous nature, and random irregularity at the liquid-solid interaction. The highest values of removal efficiencies and the considerably lowest values of energy and electrode consumption proved that the electrocoagulation technology applies in wastewater treatment containing toxic metals.•The anode electrodes were perforated to decrease the amount of electrode consumption, while the cathode electrodes were not perforated.•The new EC reactor eliminated Pb-99.73%, Cd-98.54%, and Cu-98.92% of 200 mg/l of each metal at pH 10, applied current of 1.4 A, and reaction time of 60 min. Moreover, the consumption of energy and electrodes was significantly low.•The performance indicator (R²) of the studied responses was higher than 0.95.

Keywords: Analysis and optimization; Bipolar; Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes; Electrocoagulation technology; RSM-BBD; Toxic metals.