Pollution characteristics of groundwater in an agricultural hormone-contaminated site and implementation of Fenton oxidation process

Abstract

The groundwater polluted by an agricultural hormone site was taken as the research object, and a total of 7 groundwater samples were collected at different locations in the plant. The main pollutants in the research area were determined to be extractable petroleum hydrocarbons (C₁₀-C₄₀); 1,2-dichloroethane; 1,1,2-trichloroethane; carbon tetrachloride; vinyl chloride, and chloroform; the maximum content of these pollutants can reach 271 mg/L, 1.68 × 10⁷ µg/L, 1.56 × 10⁴ µg/L, 9.53 × 10⁴ µg/L, 6.58 × 10⁴ µg/L, and 4.81 × 10⁴ µg/L, respectively. Aiming at the problems of groundwater pollution in this area, two sets of oxidation experiments have been carried out. The addition of NaHSO₃ modified Fenton oxidation system was used in this contaminated water, which enhanced (2.2 ~ 46.7%) chemical oxygen demand (COD) removal rate. The highest removal rate of extractable petroleum hydrocarbons (C₁₀-C₄₀) can reach 99%. And the degradation rate of chlorinated hydrocarbon pollutants can reach 99% to 100%, which almost achieved the purpose of complete removal. In the NaHSO₃ modified Fenton oxidation system, the addition of NaHSO₃ accelerates the cycle of Fe³⁺/Fe²⁺ and ensures the continuous existence of Fe²⁺ in the reaction system, thereby producing more ·OH and further oxidizing and degrading organic pollutants. Our work has provided important insights for this economically important treatment of this type water body and laid the foundation for the engineering of this method.

Keywords: Agricultural hormone; Fenton oxidation; Groundwater; Modified Fenton oxidation; Pollution characteristics; Sodium bisulfite.