Fe12LaO19 fabricated biochar for removal of phosphorus in water and exploration of its adsorption mechanism

Abstract

Phosphorus (P) runoff from untreated wastewater and agricultural runoff has become an issue of concern because excessive P is detrimental to the health of water bodies and aquatic organisms such as fishes. Hence, different methods are being developed to salvage this challenge. However, most of the methods are expensive, while some are unsustainable. In this study, a simple method was employed in fabricating an absorbent through the co-precipitation of iron and lanthanum on the matrix of biochar prepared from the spent coffee ground for P uptake. The adsorbent named Fe₁₂LaO₁₉@BC was able to attain equilibrium fast within 60 min when used to adsorb P with 98% P removal within the first 30 min Fe₁₂LaO₁₉@BC also maintained high P adsorption across a pH range of 3-7. In the presence of other anions (SO₄^2-, CO₃^2-, NO₃^-, Cl^-, HCO₃^-) in the solution, Fe₁₂LaO₁₉@BC enabled 71.5-97.8% uptake of P. 81.58 mg P/g maximum adsorption capacity at was reached at 40 °C. The reusability test reveals that about 60% of P uptake was maintained after five adsorption cycles with almost an undisturbed desorption efficiency. The negative value of ΔG°, as shown by the thermodynamic analysis, indicates a favorable and spontaneous reaction during P removal by Fe₁₂LaO₁₉@BC. The XRD analysis showed a major peak corresponding to Fe₁₂LaO_19, which is believed to have facilitated the adsorption of P. The adsorption was controlled by multiple mechanisms. An overview of the study indicates Fe₁₂LaO₁₉@BC as a promising adsorbent for the removal of P in the water.

Keywords: Adsorption; Biochar; Fe(12)LaO(19); Phosphorus.