Soft and Rigid Integrated Durable Coating for Large-Scale Deicing

Langmuir. 2023 Jan 10;39(1):403-410. doi: 10.1021/acs.langmuir.2c02612. Epub 2022 Dec 19.

Abstract

Soft silicone has been widely used for anti-icing coating, but the ice adhesion strength is usually scaled with the iced area at a relatively large thickness. On the other hand, a thin rigid poly(vinyl chloride) (PVC) film could be independent of the iced area and was named a low-interfacial-toughness material. Thus, a soft and rigid integrated (SRI) coating was prepared by doping PVC particles into a silicone matrix here. The introduction of PVC particles not only served as phase II to accelerate the stress concentration but also favored the formation of a wrinkle structure. After further introducing plasticizers, this SRI coating not only has a very low ice adhesion strength at a low iced length but also tends to a limit value irrespective of the iced length, which further leads to excellent large-area deicing behavior. Furthermore, the SRI coating demonstrated outstanding chemical stability, mechanical robustness, and on-field repairability.