A Review of Dry Deposition Schemes for Speciated Atmospheric Mercury

Abstract

This study reviewed the existing framework of dry deposition schemes for speciated atmospheric mercury. As the most commonly used methods for mercury dry deposition estimation, the big-leaf resistance scheme for gaseous oxidized mercury (GOM), the size distribution regarded resistance scheme for particulate bound mercury (PBM), and the bidirectional air-surface exchange scheme for gaseous elemental mercury (GEM) were introduced in detail. Sensitivity analysis were conducted to quantitatively identify the key parameters for the estimation of speciated mercury dry deposition velocities. The dry deposition velocity of GOM was found to be sensitive to the wind speed and some land use related parameters. The chemical forms of GOM could have a significant impact on the dry deposition velocity. The dry deposition velocity of PBM is sensitive to the mass fraction of PBM in coarse particles, while that of GEM is most sensitive to air temperature. Future research needs were proposed accordingly.

Keywords: Atmospheric mercury; Bidirectional exchange model; Dry deposition schemes; Resistance model; Speciation.