Airborne optical images (AOI) are often with complex sunglint reflections, which brings a certain influence to watercolor retrieval. This includes the sunglint reflection with water surface statistical distribution characteristics caused by imaging viewing angles differences, with high spatial resolution surface discrete characteristics sharing similar viewing angles, and the surface Fresnel reflection sunglint differences caused by the skylight difference during the flight of unmanned aerial vehicles. Aiming at the multiscale optical characteristics of sunglint reflection in high spatial resolution AOI, based on multi-path optical radiation transmission, the sunglint reflection interference from three different imaging processes is clarified. We developed a correction method to eliminate these different sunglint reflections on water surfaces and improve the reflectivity accuracy. The comparison with the in situ measured remote sensing reflectance of water indicated that the root mean square error (RMSE) was reduced from 0.0009 sr-1 to 0.0004 sr-1, and the mean relative error (MRE) decreased from 21.8% to 15.7%. This method has also been applied to correct the Airborne Visible Infrared Imaging Spectrometer (AVIRIS) images, showing good applicability. The method is fast, effective, and without auxiliary parameters, which provides a correction reference for different surface sunglint corrections of various AOI.