Boosting degradation and defluorination efficiencies of PFBS in a vacuum-ultraviolet/S(Ⅳ) process with iodide involvement

Abstract

Perfluorobutane sulfonate (PFBS) is considered to be a promising alternative of perfluorooctane sulfonates (PFOS), while it is also hazardous. The UV/S (Ⅳ) system has been confirmed to be effective for PFOS removal from water, while it is inefficient for PFBS decomposition. A hybrid vacuum-ultraviolet (VUV)/S (Ⅳ)/KI process was investigated for the degradation of PFBS in aqueous solution. With KI involvement, the degradation rate of PFBS was boosted from 1.8802 μg h^-1 up to 3.5818 μg h^-1 in the VUV/S (Ⅳ) process. Alkaline conditions significantly increased the degradation efficiency of PFBS, which can be explained that S (Ⅳ) was dominated by SO₃^2- rather than HSO₃^- and H₂SO₃ in alkaline conditions. Cl^-, HCO₃^-, NO₃^-, NO₂^-, and HA would inhibit the performance of the VUV/S (Ⅳ)/KI process via various reactions. In addition, the toxicity of PFBS was significantly reduced by the VUV/S (Ⅳ)/KI process. Even in actual waters, the VUV/S (Ⅳ)/KI process also presented a satisfying performance in the degradation of PFBS.

Keywords: Hydrated electron; Iodide; PFBS; Sulfite; Vacuum-ultraviolet.