Controlled Morphological Bending of 3D-FEBID Structures via Electron Beam Curing

Nanomaterials (Basel). 2022 Nov 29;12(23):4246. doi: 10.3390/nano12234246.

Abstract

Focused electron beam induced deposition (FEBID) is one of the few additive, direct-write manufacturing techniques capable of depositing complex 3D nanostructures. In this work, we explore post-growth electron beam curing (EBC) of such platinum-based FEBID deposits, where free-standing, sheet-like elements were deformed in a targeted manner by local irradiation without precursor gas present. This process diminishes the volumes of exposed regions and alters nano-grain sizes, which was comprehensively characterized by SEM, TEM and AFM and complemented by Monte Carlo simulations. For obtaining controlled and reproducible conditions for smooth, stable morphological bending, a wide range of parameters were varied, which will here be presented as a first step towards using local EBC as a tool to realize even more complex nano-architectures, beyond current 3D-FEBID capabilities, such as overhanging structures. We thereby open up a new prospect for future applications in research and development that could even be further developed towards functional imprinting.

Keywords: 3D nanoprinting; additive manufacturing; direct-write nano-fabrication; electron beam curing; electron trajectory simulations; focused electron beam induced deposition; metal nanostructures; post processing.

Grants and funding

Financial support by the Austrian Federal Ministry for Digital and Economic Affairs and the National Foundation of Research, Technology and Development is gratefully acknowledged by R.W., D.K. and H.P. (Christian Doppler Laboratory DEFINE). All authors acknowledge the infrastructure support by the Austrian Centre of Electron Microscopy and the Austrian Cooperative Research.