A novel and capable supported phenylazophenylenediamine-based nano-adsorbent for removal of the Pb, Cd, and Ni ions from aqueous solutions

Environ Sci Pollut Res Int. 2023 Mar;30(12):32762-32775. doi: 10.1007/s11356-022-24554-9. Epub 2022 Dec 5.

Abstract

Herein, we report the synthesis and characterization of chrysoidine (4-phenylazo-m-phenylenediamine) grafted on magnetic nanoparticles (Fe3O4@SiO2@CPTMS@PhAzPhDA = FeSiPAPDA) as a novel and versatile adsorbent used for the satisfactory removal of Pb, Ni, and Cd ions from contaminated water via the formation of their complexes. The Freundlich, Langmuir, Temkin, and Redlich-Patterson isotherm models were studied to reveal the adsorption capability of the adsorbent and were found out that the Langmuir model is more compatible with the nano-adsorbent behavior. Moreover, according to the ICP tests as well as based on the Langmuir isotherm, the maximum adsorption capacity of the FeSiPAPDA-based adsorbent for the Pb ions (97.58) is more than that of Cd (78.59) and Ni ions (64.03).

Keywords: Complexes; ICP test; Isotherm equation; The Langmuir model; The phenylazophenylenediamine-based adsorbent.

MeSH terms

  • Adsorption
  • Cadmium*
  • Hydrogen-Ion Concentration
  • Ions
  • Kinetics
  • Lead
  • Magnetics
  • Silicon Dioxide
  • Water
  • Water Pollutants, Chemical*

Substances

  • Cadmium
  • Lead
  • Silicon Dioxide
  • Water
  • Water Pollutants, Chemical
  • Ions