A "heat set" Zr-Diimide based Fibrous Metallogel: Multiresponsive Sensor, Column-based Dye Separation, and Iodine Sequestration

Abstract

Sensing and monitoring hazardous contaminants in water and radioactive iodine sequestration is pivotal due to their detrimental impact on biological ecosystems. In this context, herein, a water stable zirconium-diimide based metallogel (Zr@MG) with fibrous columnar morphology is accomplished through the "heat set" method. The presence of diimide linkage with long aromatic chain manifests active luminescence properties in the linker as well as in the supramolecular framework structure. The as-synthesized Zr@MG xerogel can selectively detectCr₂O₇^2- (LOD = 0.52 ppm) and 2,4,6-trinitrophenol (TNP) (LOD = 80.2 ppb) in the aqueous medium. The Zr@MG paper strip-based detection for Cr₂O₇^2- and nitro explosive makes this metallogel reliable and an attractive luminescent sensor for practical use. Moreover, a column-based dye separation experiment was performed to show selective capture of positively charged methylene blue (MB) dye with 98 % separation efficiency from the mixture of two dyes. Also, the Zr@MG xerogel showed effective iodine sequestration from the vapor phase (232 wt%).

Keywords: Diimide; Iodine sequestration; Metallogel; Nitro-explosive; Sensing.