Comprehensive effects of grain-size modification of electrolytic manganese residue on deep dehydration performance and microstructure of sludge

Abstract

As the by-product accompanied by sewage treatment, sludge has complex composition and high moisture content, therefore, its reutilization and disposal are still a challenge. In this paper, five kinds of quartz sand conditioners with different particle sizes (denoted as QS1, QS2, QS3, QS4 and QS5, respectively) were used to explore the effect of particle size distribution of conditioners on sludge dewatering performance. The moisture content, capillary suction time (CST), time to filter (TTF), specific resistance of filtration (SRF), particle size distribution curve, pore distribution law, scanning electron microscopy, isothermal adsorption-desorption curve and extracellular polymeric substances distribution were employed to characterize the modified sludge and explore the improvement mechanism. The results show that the particle size distribution of the conditioner significantly affects the efficiency of sludge dewatering. The wt% of sludge regulated with QS1 (QS1-S) could be reduced to 52%, and its CST value, TTF value and SRF value is 57.93 s, 278 s and 1.84 × 10⁸ s² g^-1, respectively. The conjecture about the effect of difference of particle size distribution on sludge dewatering performance was verified with the original Electrolytic Manganese Residue (EMR) and the grain-size modified Electrolytic Manganese Residue (EMR6). Compared with those of the EMR-conditioned sludge, the CST, TTF and SRF of EMR6-conditioned sludge was decreased by 8.7%, 22.3% and 11.2%, respectively. According to analysis of surface microstructure, the surface of the sludge cake modified with QS1 is rough and sparse with rich pore structure. Compared with those of the undisturbed sludge (A0), the pore volume and specific surface area of the sludge modified with QS1 was increased by 61.65% and 38.62%, respectively. After grain-size modification, the dehydration effect of EMR6 (D10 4.25 μm, D50 19.65 μm, D90 73.26 μm) was significantly enhanced, and the D10, D50 and D90 value was close to that of QS1. It can be concluded that the particle size of QS1 (D10 3.27 μm, D50 15.66 μm, and D90 62.23 μm) can improve the dewatering performance of sludge by shearing the sludge particles to change the original sludge particle size distribution and improving the blockage of sludge dewatering channels.

Keywords: Dewatering; Electrolytic manganese residue; Filtration; Particle size; Sewage sludge.