Chiral Au Nanorods: Synthesis, Chirality Origin, and Applications

ACS Nano. 2022 Dec 27;16(12):19789-19809. doi: 10.1021/acsnano.2c08145. Epub 2022 Dec 1.

Abstract

Chiral Au nanorods (c-Au NRs) with diverse architectures constitute an interesting nanospecies in the field of chiral nanophotonics. The numerous possible plasmonic behaviors of Au NRs can be coupled with chirality to initiate, tune, and amplify their chiroptical response. Interdisciplinary technologies have boosted the development of fabrication and applications of c-Au NRs. Herein, we have focused on the role of chirality in c-Au NRs which helps to manipulate the light-matter interaction in nontraditional ways. A broad overview on the chirality origin, chirality transfer, chiroptical activities, artificially synthetic methodologies, and circularly polarized applications of c-Au NRs will be summarized and discussed. A deeper understanding of light-matter interaction in c-Au NRs will help to manipulate the chirality at the nanoscale, reveal the natural evolution process taking place, and set up a series of circularly polarized applications.

Keywords: Au nanorods; chiral nanophotonics; chiral plasmonic nanosensors; chirality transfer; chiroptical activity; circularly polarized photocatalysis; plasmonic chirality; surface plasmon resonance.

Publication types

  • Review