Novel Supercapacitor Electrode Derived from One Dimensional Cerium Hydrogen Phosphate (1D-Ce(HPO4)2.xH2O)

Molecules. 2022 Nov 9;27(22):7691. doi: 10.3390/molecules27227691.

Abstract

In this manuscript, we are reporting for the first time one dimensional (1D) cerium hydrogen phosphate (Ce(HPO4)2.xH2O) electrode material for supercapacitor application. In short, a simple hydrothermal technique was employed to prepare Ce(HPO4)2.xH2O. The maximum surface area of 82 m2 g-1 was obtained from nitrogen sorption isotherm. SEM images revealed Ce(HPO4)2.xH2O exhibited a nanorod-like structure along with particles and clusters. The maximum specific capacitance of 114 F g-1 was achieved at 0.2 A g-1 current density for Ce(HPO4)/NF electrode material in a three-electrode configuration. Furthermore, the fabricated symmetric supercapacitor (SSC) based on Ce(HPO4)2.xH2O//Ce(HPO4)2.xH2O demonstrates reasonable specific energy (2.08 Wh kg-1), moderate specific power (499.88 W kg-1), and outstanding cyclic durability (retains 92.7% of its initial specific capacitance after 5000 GCD cycles).

Keywords: cerium hydrogen phosphate; nanorods; specific energy; specific power; stability.

MeSH terms

  • Cerium*
  • Electric Capacitance
  • Electrodes
  • Hydrogen*
  • Phosphates

Substances

  • Hydrogen
  • cerium phosphate
  • Phosphates
  • Cerium

Grants and funding

APC was sponsored by MDPI.