Coordinative Combination of Nitroamine and Gem-Dinitromethyl with Fused Ring for Enhanced Oxygen Balances and Detonation Properties

Xun Zhang; Yaxi Wang; Xinyuan Zhao; Chunlin He; Siping Pang

doi:10.3390/ijms232214337

Coordinative Combination of Nitroamine and Gem-Dinitromethyl with Fused Ring for Enhanced Oxygen Balances and Detonation Properties

Int J Mol Sci. 2022 Nov 18;23(22):14337. doi: 10.3390/ijms232214337.

Authors

Xun Zhang^{1

2}, Yaxi Wang^{1

2}, Xinyuan Zhao^{1

2}, Chunlin He^{1

2

3

4}, Siping Pang¹

Affiliations

¹ School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
² Experimental Center of Advanced Materials, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
³ Yangtze Delta Region Academy, Beijing Institute of Technology, Jiaxing 314019, China.
⁴ Chongqing Innovation Center, Beijing Institute of Technology, Chongqing 401120, China.

Abstract

Oxygen balance and heat of formation are closely related to the nitrogen and oxygen content in a molecule and have a significant effect on the detonation performance of energetic materials. Here a new family of 1,2,4-triazolo [4,3-b][1,2,4,5]-tetrazine containing gem-dinitromethyl and nitroamine with high nitrogen-oxygen content was synthesized and characterized. Moreover, the structure of the guanidine salt (3) and TATOT salt (4) were confirmed by single-crystal X-ray diffraction. The nitrogen and oxygen content of ammonium salt 2 reached 82.5%, with a high density (1.805 g cm^-3) and high detonation properties (D = 8900 m s^-1; P = 32.4 GPa), which were similar to those of RDX.

Keywords: gem-dinitromethyl; high nitrogen-oxygen content; nitroamine; triazolo-tetrazine fused ring.

MeSH terms

Blood Gas Analysis
Crystallography, X-Ray
Guanidines
Nitrogen*
Oxygen* / chemistry

Substances

Oxygen
Nitrogen
Guanidines

Abstract

MeSH terms

Substances

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