Novel proton exchange membranes consisting of sulfonated polystyrene ethylene butylene polystyrene (sPSEBPS), sulfonated poly ether sulfone (SPES) and hexagonal boron nitride (hBN) were fabricated using a facile solution casting technique. The PSEBPS polymer was functionalized using chlorosulfonic acid as the sulfonating agent. Polymerization was typically conducted by taking three different monomers, namely 3,6-dihydroxy naphthalene-2,7-disulfonic acid disodium salt, 4,4'-dichlorodiphenyl sulfone, and bisphenol-A, to yield sulfonated poly ether sulfone (SPES). The resultant SPES polymer was blended with sPSEBPS followed by incorporation with an appropriate quantity of hBN. The physicochemical and structural properties of the membranes were studied in order to evaluate their compatibility with fuel cell applications. X-Ray photoelectron spectroscopy data validated the successful incorporation of the filler into the polymer matrix. Water absorption of the membranes was found in the range between 19.5 and 29.8%. The membrane loaded with 4.0 wt% of hBN showed the maximum ion-exchange capacity of 1.21 meq g-1, whereas the control sPSEBPS/SPES membrane was restricted to 0.48 meq g-1. The composite membrane loaded with hBN displayed higher thermal stability than that of the control sample. The sPSEBPS/SPES/hBN-4 composite membrane exhibited an ionic conductivity of 0.0329 S cm-1 at 30 °C. Overall, the experimental data of the prepared composite membranes revealed that the materials are potential candidates for fuel cells.