One-step preparation of MoOx/ZnS/ZnO composite and its excellent performance in piezocatalytic degradation of Rhodamine B under ultrasonic vibration

Abstract

This paper synthesized a new type of ternary piezoelectric catalyst MoO_x/ZnS/ZnO (MZZ) by a one-step method. The catalytic degradation of Rhodamine B (RhB) solution (10 µg/g, pH = 7.0) shows that the composite catalyst has excellent piezoelectric catalytic activity under ultrasonic vibration (40 kHz). The piezoelectric degradation rate of the optimal sample reached 0.054 min^-1, which was about 2.5 times that of pure ZnO. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS) technologies were used to analyze the structure, morphology, and interface charge transfer properties of the MZZ piezocatalysts. The results showed that the composite catalyst may have a core-shell structure. ZnS is coated on the surface of ZnO, while MoO_x adheres to the surface of ZnS. This structure endowed MZZ larger specific surface area than ZnO, which benefits the RhB adsorption. More importantly, the formed heterojunction structure between ZnS and ZnO promotes the separation of positive and negative charges induced by the piezoelectric effect. MoO_x species may act as a charge trap to further promote more carriers to participate in the reaction. In addition, MoO_x may also be beneficial in adsorbing dyes. Active species capture experiments show that superoxide radicals and holes are the main active species in piezoelectric catalytic reactions on MZZ catalysts.

Keywords: Core-shell structure; MoO(x); Piezocatalytic; Rhodamine B; ZnO; ZnS.