The development of electrocatalysts with high-efficiency and clear structure-activity relationship towards the sluggish oxygen evolution reaction (OER) is essential for the wide application of water electrolyzers. Recently, the dynamic reconstruction phenomenon of the catalysts' surface structures during the OER process has been discovered. With the help of various advanced ex situ and in situ characterization, it is demonstrated that such surface reconstruction could yield actual active species to catalyze the water oxidation process. However, the attention and studies of potential interaction between reconstructed species and substrate are lacking. This review summarizes the recent development of typical reconstructed electrocatalysts and the substrate effect. First, the advanced characterization for electrocatalytic reconstruction is briefly discussed. Then, typical reconstructed electrocatalysts are comprehensively summarized and the key role of substrate effects during the OER process is emphasized. Finally, the future challenges and perspectives of surface reconstructed catalysts for water electrolysis are discussed.
Keywords: alkaline electrolyte; oxygen evolution reaction; reconstruction phenomenon; substrate effect; water electrolysis.
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