The research analyzes technological properties and stability of innovative gel-forming polymeric materials for complex soil conditioning. These materials combine improvements in the water retention, dispersity, hydraulic properties, anti-erosion and anti-pathogenic protection of the soil along with a high resistance to negative environmental factors (osmotic stress, compression in the pores, microbial biodegradation). Laboratory analysis was based on an original system of instrumental methods, new mathematical models, and the criteria and gradations of the quality of gels and their compositions with mineral soil substrates. The new materials have a technologically optimal degree of swelling (200−600 kg/kg in pure water and saline solutions with 1−3 g/L TDS), high values of surface energy (>130 kJ/kg), specific surface area (>600 m2/g), threshold of gel collapse (>80 mmol/L), half-life (>5 years), and a powerful fungicidal effect (EC50 biocides doses of 10−60 ppm). Due to these properties, the new gel-forming materials, in small doses of 0.1−0.3% increased the water retention and dispersity of sandy substrates to the level of loams, reduced the saturated hydraulic conductivity 20−140 times, suppressed the evaporation 2−4 times, and formed a windproof soil crust (strength up to 100 kPa). These new methodological developments and recommendations are useful for the complex laboratory testing of hydrogels in small (5−10 g) soil samples.
Keywords: basal respiration; biodegradation; half-life of polymers; hydraulic conductivity; mathematical modeling; soil aggregation; specific surface area; surface energy; synthetic polymer hydrogels; thermodynamic water potential; water retention.