To enhance the permeation and separation performance of the polyethersulfone (PES) tight ultrafiltration (TUF) membrane, two-dimensional molybdenum disulfide (MoS2) was applied as a modifier in low concentrations. The influence of different concentrations of MoS2 (0, 0.25, 0.50, 1.00, and 1.50 wt%) on TUF membranes was investigated in terms of morphology, mechanical strength properties, permeation, and separation. The results indicate that the blending of MoS2 tailored the microstructure of the membrane and enhanced the mechanical strength property. Moreover, by embedding an appropriate amount of MoS2 into the membrane, the PES/MoS2 membranes showed improvement in permeation and without the sacrifice of the rejection of bovine serum protein (BSA) and humic acid (HA). Compared with the pristine membrane, the modified membrane embedded with 0.5 wt% MoS2 showed a 36.08% increase in the pure water flux, and >99.6% rejections of BSA and HA. This study reveals that two-dimensional MoS2 can be used as an effective additive to improve the performance and properties of TUF membranes for water treatment.
Keywords: BSA rejection; humic acid rejection; molybdenum disulfide; tight ultrafiltration membrane.