In this research, different clays such as laponite and montmorillonite (NaMMT) are used as fillers in the preparation of thermoplastic starch/clay nanocomposites. Thin films are produced by casting and evaporation in a wide composition range, using glycerol as the plasticizer at two different concentrations. The surface energy of clay fillers is measured by inverse gas chromatography (IGC); X-ray diffraction (XRD) and light transmission measurements (UV-VIS) are carried out to characterize the structure of nanocomposites; and mechanical properties and water vapor permeability are also studied. While all the starch/montmorillonite nanocomposites possess intercalated structures, significant exfoliation can be noted in the starch/laponite nanocomposites, mainly at low clay contents. Due to the larger surface energy of montmorillonite, stronger polymer/clay interactions and better mechanical properties can be assumed in starch/NaMMT composites. The smaller surface energy of laponite, however, can facilitate the delamination of laponite layers. Thus, the specific surface area of laponite can be further increased by exfoliation. Based on the results, the better exfoliation and the much larger specific surface area of laponite lead to higher reinforcement in starch/laponite nanocomposites.
Keywords: laponite; mechanical properties; montmorillonite; reinforcing effect; starch/clay nanocomposite; structure.