Release of millions of micro(nano)plastic fragments from photooxidation of disposable plastic boxes

Abstract

The widespread use of disposable plastic boxes is exacerbating the dangers of microplastics (MPs); however, little is known about the fragmentation behavior of MPs during aging. In this study, the dynamic evolution on the release of micro(nano)plastics and photoaging properties of two disposable plastic boxes (polypropylene (PP) and polystyrene (PS)) were investigated under light irradiation and mechanical abrasion. Results showed that the weight of PP and PS was decreased by 53 % and 100 %, respectively after 60 d of ultraviolet irradiation (UV60). Moreover, a large number of fragmented particles were produced from the combined light irradiation and abrasion, with 0.142 ± 0.006 and 0.141 ± 0.013 million micro(nano)plastics/mL particles from PP and PS boxes, respectively, and the nanometer range (<100 nm) accounted for 70.8 % and 46.8 %. The correlation model of the average size or alteration time versus carbonyl index (CI) was developed, which indicated that the fragmentation behavior was mainly related to the photooxidation, though mechanical abrasion also played a certain enhancing role. Additionally, PS was susceptible to the fragmentation and photooxidation compared to PP possibly since the phenyl ring of PS was more vulnerable to UV attack than the methyl of PP. The findings of this study clarify the dynamic fragmentation process of micro(nano)plastics of disposable plastic boxes and provide useful information to access environmental fate of MPs more holistically.

Keywords: Disposable boxes; Fragmentation; Mechanical abrasion; Micro(nano)plastics; Photooxidation.