Polarisation-driven magneto-optical and nonlinear-optical behaviour of a room-temperature ferroelectric nematic phase

Soft Matter. 2022 Nov 30;18(46):8804-8812. doi: 10.1039/d2sm01298g.

Abstract

Nematics with a broken polar symmetry are one of the fascinating recent discoveries in the field of soft matter. High spontaneous polarisation and the fluidity of the ferroelectric nematic NF phase make such materials attractive for future applications and interesting for fundamental research. Here, we explore the polar and mechanical properties of a room-temperature ferroelectric nematic and its behaviour in a magnetic field. We show that NF is much less susceptible to the splay deformation than to the twist. The strong splay rigidity can be attributed to the electrostatic self-interaction of polarisation avoiding the polarisation splay.