Emergent properties from CuPd alloy films under near-infrared excitation

Gregory A Manoukian; Orhan Kizilkaya; Sergi Lendinez; Luis D B Manuel; Tiago R Leite; Karunya S Shirali; William A Shelton; Phillip T Sprunger; Jason B Baxter; Kevin M McPeak

doi:10.1063/5.0102066

Emergent properties from CuPd alloy films under near-infrared excitation

J Chem Phys. 2022 Nov 7;157(17):174702. doi: 10.1063/5.0102066.

Affiliations

¹ Department of Chemical and Biological Engineering, Drexel University, Philadelphia, Pennsylvania 19104, USA.
² Center for Advanced Microstructures and Devices, Louisiana State University, Baton Rouge, Louisiana 70806, USA.
³ Gordon and Mary Cain Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, USA.
⁴ Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803, USA.

PMID: 36347709
DOI: 10.1063/5.0102066

Abstract

Noble-transition metal alloys offer emergent optical and electronic properties for near-infrared (NIR) optoelectronic devices. We investigate the optical and electronic properties of Cu_xPd_1-x alloy thin films and their ultrafast electron dynamics under NIR excitation. Ultraviolet photoelectron spectroscopy measurements supported by density functional theory calculations show strong d-band hybridization between the Cu 3d and Pd 4d bands. These hybridization effects result in emergent optical properties, most apparent in the dilute Pd case. Time-resolved terahertz spectroscopy with NIR (e.g., 1550 nm) excitation displays composition-tunable electron dynamics. We posit that the negative peak in the normalized increment of transmissivity (ΔT/T) below 2 ps from dilute Pd alloys is due to non-thermalized hot-carrier generation. On the other hand, Pd-rich alloys exhibit an increase in ΔT/T due to thermalization effects upon ultrafast NIR photoexcitation. Cu_xPd_1-x alloys in the dilute Pd regime may be a promising material for future ultrafast NIR optoelectronic devices.