([2.2.2]Cryptand)potassium (4-methyl-benzene-thiol-ato)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyr-inato]manganate(II) tetra-hydro-furan disolvate

Yiwen Yuan; Jianfeng Li

doi:10.1107/S2414314622002413

([2.2.2]Cryptand)potassium (4-methyl-benzene-thiol-ato)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyr-inato]manganate(II) tetra-hydro-furan disolvate

IUCrdata. 2022 Mar 8;7(Pt 3):x220241. doi: 10.1107/S2414314622002413. eCollection 2022 Mar.

Authors

Yiwen Yuan¹, Jianfeng Li¹

Affiliation

¹ College of Materials Science and Opto-electronic Technology, CAS Center for Excellence in Topological Quantum Computation & Center of, Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Yanqi Lake, Huairou District, Beijing 101408, People's Republic of China.

Abstract

Single crystals of the title compound, [K(C₁₈H₃₆N₂O₆)][Mn(C₄₄H₂₄Cl₄N₄)(C₇H₇S)]·2C₄H₈O, were obtained by the solvent evaporation method. The Mn^II cation is coordinated by four pyrrole N atoms (N_p) of the porphyrin ring and one S atom of the apical 4-methyl-benzene-thiol-ate ligand with the average Mn-N_p and the apical Mn-S bond lengths being 2.160 (9) and 2.4642 (8) Å, respectively. Two tetra-hydro-furan solvent mol-ecules and a potassium cation chelated inside a [2.2.2]cryptand (4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo[8.8.8]hexa-cosa-ne) are also present.

Keywords: 4-methylbenzenethiolate; MnII porphyrin; crystal structure.

Grants and funding

The authors thank the National Natural Science Foundation of China (grant No. 21977093 to JL) for support. This work was supported in part by the Strategic Priority Research Program of Chinese Academy of Sciences, grant No. XDB28000000.