12-Ethyl-6a,10a-di-hydro-5 H-6-oxachrysene

IUCrdata. 2020 Mar 5;5(Pt 3):x200286. doi: 10.1107/S2414314620002862. eCollection 2020 Mar.

Abstract

In the title compound, C19H16O, the pyran ring is in a half-chair conformation. The essentially planar naphthalene ring system (r.m.s. deviation = 0.020 Å) forms a dihedral angle of 14.37 (5)° with the fused benzene ring. In the crystal, pairs of mol-ecules are connected into inversion dimers by weak C-H⋯O hydrogen bonds to generate R 2 2(6) loops.

Keywords: crystal structure; fused-rings; regioisomer; weak hydrogen bonds.