Simultaneous Regulation of Solvation Shell and Oriented Deposition toward a Highly Reversible Fe Anode for All-Iron Flow Batteries

Abstract

Developing low-cost all-iron hybrid redox flow batteries (RFBs) presents a practical alternative to the high-cost all-vanadium RFBs and is deemed vital for grid-scale energy storage applications. However, the intrinsically poor Fe anode reversibility associated with the deposition and dissolution of metallic iron greatly limits the cycling performance and long-term stability of all-iron hybrid RFBs. Herein, a highly reversible and dendrite-free Fe anode is reported for all-iron RFBs through regulation of polar solvent dimethyl sulfoxide (DMSO) on FeCl₂ anolyte, which simultaneously reshapes Fe²⁺ solvation structure and induces controllable oriented Fe deposition. Combining both experimental and theoretical analyses, the polar DMSO additives prove effective in replacing H₂ O molecule from the primary solvation shell of Fe²⁺ cation via the Fe²⁺ -O (DMSO) bond and meanwhile induces a fine-grained Fe nucleation on the preferred Fe (110) plane, which are responsible for the minimized hydrogen evolution and dendrite-free Fe deposition that significantly enhance Fe anode reversibility. The all-iron RFB based on the proposed FeCl₂ -DMSO anolyte demonstrates an excellent combination of peak power density of 134 mW cm^-2 , high energy efficiency of 75% at 30 mA cm^-2 , and high capacity retention of 98.6% over 200 cycles, which presents the best performance of all-iron RFBs among previously reported research.

Keywords: Fe anodes; flow batteries; oriented deposition; polar solvents; solvation shells.