Rogue waves (RWs) are extreme and rare waves that emerge unexpectedly in many natural systems and their formation mechanism and prediction have been extensively studied. Here, we numerically demonstrate the appearance of extreme events (EEs) for the first time, to the best of our knowledge, in the chaotic regimes of a two-element coupled semiconductor laser array. Based on coupled-mode theory, we characterize the occurrence of EEs by calculating the probability distribution, which confirms the RW-type feature of the intensity pulses, i.e., non-Gaussian distribution. Combining with the results of the 0-1 test for chaos, we confirm that EEs originate from deterministic nonlinearities in coupled semiconductor laser systems. We show that EEs can be predicted with a long anticipation time. Furthermore, simulation results manifest that the occurrence probability of EEs can be flexibly tuned by tailoring the coupling parameter space. With the help of two-dimension maps, the effects of key parameters, i.e., the waveguide structure and the pump level, on the formation of EEs are discussed systematically. This work provides a new platform for the research of EEs in a highly integrated structure and opens up a novel investigation field for coupled semiconductor laser arrays.