Excitation of "forbidden" guided-wave plasmon polariton modes via direct reflectance using a low refractive index polymer coupling layer

PLoS One. 2022 Oct 26;17(10):e0276522. doi: 10.1371/journal.pone.0276522. eCollection 2022.

Abstract

A surface plasmon polariton (SPP) is an excitation resulting from the coupling of light to a surface charge oscillation at a metal-dielectric interface. The excitation and detection of SPPs is foundational to the operating mechanism of a number of important technologies, most of which require SPP excitation via direct reflectance, commonly achieved via Attenuated Total Reflection (ATR) using the Kretschmann configuration. As a result, the accessible modes are fundamentally high-loss "leaky modes," presenting a critical performance barrier. Recently, our group provided the first demonstration of "forbidden," or guided-wave plasmon polariton modes (GW-PPMs), collective modes of a MIM structure with oscillatory electric field amplitude in the central insulator layer with up to an order of magnitude larger propagation lengths than those of traditional SPPs. However, in that work, GW-PPMs were accessed by indirect reflectance using Otto configuration ATR, making them of limited applied relevance. In this paper, we demonstrate a technique for direct reflectance excitation and detection of GW-PPMs. Specifically, we replace the air gap used in traditional Otto ATR with a low refractive index polymer coupling layer, mirroring a technique previously demonstrated to access Long-Range Surface Plasmon Polariton modes. We fit experimental ATR data using a robust theoretical model to confirm the character of the modes, as well as to explore the potential of this approach to enable advantageous propagation lengths. The ability to excite GW-PPMs using a device configuration that does not require an air gap could potentially enable transformative performance enhancements in a number of critical technologies.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Metals / chemistry
  • Models, Theoretical
  • Polymers
  • Refractometry*
  • Surface Plasmon Resonance* / methods

Substances

  • Polymers
  • Metals

Grants and funding

This work was supported by internal funding from Western Washington University (WWU) and the WWU Advanced Materials Science and Engineering Center (AMSEC). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.