Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds

Fei Wang; Ying Chen; Weidong Rao; Shu-Su Shen; Shun-Yi Wang

doi:10.1039/d2cc04512e

Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds

Chem Commun (Camb). 2022 Nov 10;58(90):12564-12567. doi: 10.1039/d2cc04512e.

Authors

Fei Wang¹, Ying Chen¹, Weidong Rao², Shu-Su Shen³, Shun-Yi Wang¹

Affiliations

¹ Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou, Jiangsu, 215123, China. shunyi@suda.edu.cn.
² Key Laboratory of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China.
³ School of Environmental Science and Engineering, Suzhou University of Science and Technology, No. 99, Xuefu road, Huqiu district, Suzhou, 215009, P. R. China.

PMID: 36278966
DOI: 10.1039/d2cc04512e

Abstract

A Cu-catalyzed cascade reaction of four-membered silacyclobutanes (SCBs) and thiosulfonates to construct S (Se)-containing organosilicon compounds was developed. The protocol shows a wide range of substrate scope, high functional group compatibility and mild reaction conditions. New C-S (Se) and Si-O bonds were constructed in one step.