Revealing the Magnetic Structure and Properties of Mn(Co,Ge)2

Inorg Chem. 2022 Nov 7;61(44):17673-17681. doi: 10.1021/acs.inorgchem.2c02758. Epub 2022 Oct 21.

Abstract

The atomic and magnetic structures of Mn(Co,Ge)2 are reported herein. The system crystallizes in the space group P63/mmc as a superstructure of the MgZn2-type structure. The system exhibits two magnetic transitions with associated magnetic structures, a ferromagnetic (FM) structure around room temperature, and an incommensurate structure at lower temperatures. The FM structure, occurring between 193 and 329 K, is found to be a member of the magnetic space group P63/mm'c'. The incommensurate structure found below 193 K is helical with propagation vector k = (0 0 0.0483). Crystallographic results are corroborated by magnetic measurements and ab initio calculations.