Free energy calculation of small molecules or ion species in aqueous solvent is one of the most important problems in electrochemistry study. Although there are many previous approaches to calculate such free energies, they are based on ab initio methods and suffer from various limitations and approximations. In the current work, we developed a hybrid approach based on ab initio molecular dynamics (AIMD) simulations to calculate the ion solvation energy. In this approach, a small water cluster surrounding the central ion is used, and implicit solvent model is applied outside the water cluster. A dynamic potential well is used during AIMD to keep the water cluster together. Quasi-harmonic approximation is used to calculate the entropy contribution, while the total energy average is used to calculate the enthalpy term. The obtained solvation voltages of the bulk metal agree with experiments within 0.3 eV, and the simulation results for the solvation energies of gaseous ions are close to the experimental observations. Besides the free energies, radial pair distribution functions and coordination numbers of hydrated cations are also obtained. The remaining challenges of this method are also discussed.