Silicon carbide catalytic ceramic membranes with nano-wire structure for enhanced anti-fouling performance

Abstract

Membrane fouling is a critical challenge for current ceramic membranes, which suffer from low flux and insufficient removal. Development of self-cleaning catalytic ceramic membranes is promising to address this challenge. Herein, we design heterogeneous silicon carbide ceramic membranes featuring a novel structure of g-C₃N₄-decorated β-SiC nano-wire catalytic functional layer, which enables enhanced anti-fouling self-cleaning performance. At chemical harsh (alkaline or especially acidic) conditions, the nano-wire membrane exhibits catalysis-enhanced removal performance for organic contaminants. Unlike conventional particle-packing membrane structure, such a nano-wire network membrane structure has not only high porosity (56.1%), but exceptional water permeance (110 L·m^-2·h^-1·bar^-1) and removal (100%) of organic substance under simulated sunlight, outperforming state-of-the-art organic membranes and ceramic membranes. Superoxide radical (∙O₂^-) was experimentally confirmed to be major reactive species responsible for self-cleaning function. We also propose a catalytic mechanism model with radical formation pathway, enabled by the as-formed g-C₃N₄@β-SiC heterojunction structure with reduced electron-hole recombination. This work would provide new insights into not only rational design of next-generation ceramic membranes with self-cleaning function but also more applications of efficient treatment of refractory wastewaters containing degradable organic substances by using such membranes.

Keywords: Ceramic membrane; Nano-wire; Self-cleaning; Silicon carbide; Water treatment.