Sources, transport, and visibility impact of ambient submicrometer particle number size distributions in an urban area of central Taiwan

Li-Hao Young; Chih-Sheng Hsu; Ta-Chih Hsiao; Neng-Huei Lin; Si-Chee Tsay; Tang-Huang Lin; Wen-Yinn Lin; Chau-Ren Jung

doi:10.1016/j.scitotenv.2022.159070

Sources, transport, and visibility impact of ambient submicrometer particle number size distributions in an urban area of central Taiwan

Sci Total Environ. 2023 Jan 15;856(Pt 2):159070. doi: 10.1016/j.scitotenv.2022.159070. Epub 2022 Sep 27.

Authors

Li-Hao Young¹, Chih-Sheng Hsu², Ta-Chih Hsiao³, Neng-Huei Lin⁴, Si-Chee Tsay⁵, Tang-Huang Lin⁶, Wen-Yinn Lin⁷, Chau-Ren Jung⁸

Affiliations

¹ Department of Occupational Safety and Health, China Medical University, 100, Sec. 1, Jingmao Rd., Beitun Dist., Taichung 406040, Taiwan. Electronic address: lhy@mail.cmu.edu.tw.
² Department of Occupational Safety and Health, China Medical University, 100, Sec. 1, Jingmao Rd., Beitun Dist., Taichung 406040, Taiwan.
³ Graduate Institute of Environmental Engineering, National Taiwan University, 1, Sec. 4, Roosevelt Rd., Taipei 10617, Taiwan.
⁴ Department of Atmospheric Sciences, National Central University, 300, Zhongda Rd., Zhongli Dist., Taoyuan 320317, Taiwan.
⁵ NASA Goddard Space Flight Center, Greenbelt, MD 20771, USA.
⁶ Center for Space and Remote Sensing Research, National Central University, 300, Zhongda Rd., Zhongli Dist., Taoyuan 320317, Taiwan.
⁷ Institute of Environmental Engineering and Management, National Taipei University of Technology, 1, Sec. 3, Chung-Hsiao E. Rd., Taipei 106344, Taiwan.
⁸ Department of Public Health, China Medical University, 100, Sec. 1, Jingmao Rd., Beitun Dist., Taichung 406040, Taiwan.

PMID: 36179847
DOI: 10.1016/j.scitotenv.2022.159070

Abstract

This study applied positive matrix factorization (PMF) to identify the sources of size-resolved submicrometer (10-1000 nm) particles and quantify their contributions to impaired visibility based on the particle number size distributions (PNSDs), aerosol light extinction (b_p), air pollutants (PM₁₀, PM_2.5, SO₂, O₃, and NO), and meteorological parameters (temperature, relative humidity, wind speed, wind direction, and ultraviolet index) measured hourly over an urban basin in central Taiwan between 2017 and 2021. The transport of source-specific PNSDs was evaluated with wind and back trajectory analyses. The PMF revealed six sources to the total particle number (TPN), surface (TPS), volume (TPV), and b_p. Factor 1 (F1), the key contributor to TPN (35.0 %), represented nucleation (<25 nm) particles associated with fresh traffic emission and secondary new particle formation, which were transported from the west-southwest by stronger winds (>2.2 m s^-1). F2 represented the large Aitken (50-100 nm) particles transported regionally via northerly winds, whereas F3 represented large accumulation (300-1000 nm) particles, which showed elevated concentrations under stagnant conditions (<1.1 m s^-1). F4 represented small Aitken (25-50 nm) particles arising from the growth and transport of the nucleation particles (F1) via west-southwesterly winds. F5 represented large Aitken particles originating from combustion-related SO₂ sources and carried by west-northwesterly winds. F6 represented small accumulation (100-300 nm) particles emitted both by local sources and by the remote SO₂ sources found for F5. Overall, large accumulation particles (F3) played the greatest role in determining the TPV (66.4 %) and TPS (34.8 %), and their contribution to b_p increased markedly from 17.3 % to 40.7 % as visibility decreased, indicating that TPV and TPS are better metrics than TPN for estimating b_p. Furthermore, slow-moving air masses-and therefore stagnant conditions-facilitate the build-up of accumulation mode particles (F3 + F6), resulting in the poorest visibility.

Keywords: Aerosol light extinction; Back trajectory; Cluster analysis; Local source; Regional transport; Source apportionment.

MeSH terms

Air Pollutants* / analysis
Air Pollution* / analysis
Environmental Monitoring / methods
Particle Size
Particulate Matter / analysis
Taiwan

Substances

Particulate Matter
Air Pollutants