ZIF-8 metal organic framework composites as hydrogen evolution reaction photocatalyst: A review of the current state

Abstract

In the past decade, extensive research has been devoted to synthesis of ZIF-8 materials for catalytic applications. As physico-chemical properties are synthesis-dependent, this review explores different synthesis strategies based the solvent and solvent-free synthesis of zeolitic imidazole framework. Accordingly, the effect of several parameters on the ZIF-8 synthesis were discussed including solvent, deprotonating agents, precursors ratio is delivered. Additionally, the advantages and disadvantages of each synthesis have been discussed and assessed. ZIF-8 textural and structural properties justify its wide use as a stable high surface area MOF in aqueous catalytic reactions. This review includes the applicatios of ZIF-8 materials in photocatalytic hydrogen evolution reaction (HER). The efficiency of the reviewed materials was fairly assessed. Finally, Limitations, drawbacks and future challenges were fully debated to ensure the industrial viability of the ZIFs.

Keywords: Hydrogen evolution reaction; Photocatalysis; ZIF-8 synthesis; Zeolite imidazole framework-8 (ZIF-8).