In this work, CdWO4 (CWO), CWO: Ag, and CWO: Gd nanoparticles (NPs) were synthesized by a simple method. Incorporation of the prepared NPs in a polymeric matrix (Polyester) developed a highly luminescent and ionizing ray nanocomposite sensor. Results from XRD, XPS, FE-SEM and EDAX, verified the successful synthesize of pure and doped CWO nanoparticles with the mean size of approximately 50-70 nm. The luminescence properties of the synthesized NPs were examined under UV and ion-beam excitation. CWO: Ag nanoparticles exhibited the most intense emission in the blue-green range compared to the CWO and CWO: Gd samples. The scintillation response of the prepared composite films against alpha irradiation (241Am source) was studied. The highest absolute efficiency (ε) was obtained for CWO: Ag composite film (58.18%) which has promising applications in flexible and transparent optical detectors.
Keywords: CdWO(4) nanoparticles; composite film; doped CWO; luminescence; scintillation.
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