Highly qualified InP based QDs through a temperature controlled ZnSe shell coating process and their DFT calculations

Haewoon Seo; Ju Hyun Park; O-Hoon Kwon; O Pil Kwon; Sang Kyu Kwak; Sang-Wook Kim

doi:10.1039/d0na00451k

Highly qualified InP based QDs through a temperature controlled ZnSe shell coating process and their DFT calculations

Nanoscale Adv. 2020 Oct 15;2(12):5615-5622. doi: 10.1039/d0na00451k. eCollection 2020 Dec 15.

Authors

Haewoon Seo¹, Ju Hyun Park², O-Hoon Kwon¹, O Pil Kwon¹, Sang Kyu Kwak², Sang-Wook Kim¹

Affiliations

¹ Department of Molecular Science and Technology, Ajou University Suwon 443-749 Korea.
² Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST) 50 UNIST-gil Ulsan 44919 Republic of Korea.

Abstract

For QDs used in displays, a narrow emission linewidth and emission peak tuning depending on the morphology of the QDs are the most important factors in order to maximize the range of colors to be represented. CdSe-based QDs are known as the most suitable QDs for displays, but cadmium is a highly toxic and regulated substance for use worldwide; InP-based QDs are the most noteworthy alternative. However, InP-based QDs have a wider linewidth of emission light in the entire visible region compared to CdSe-based QDs. In this work, we use the ZnSe inner shell as a lattice buffer layer between the InGaP core and the ZnS outer shell in the type-I structure, using a heating-up method in which ZnSe precursors were added to a low-temperature core solution and then rapidly raised to a temperature of 270-320 °C. Interestingly, when reacting at high temperatures, the shape of the QDs changes to a tetrahedron, and the FWHM becomes narrower than at low temperature. To understand this phenomenon, we proceeded with transmission electron microscopy (TEM) and powder X-ray diffraction (PXRD) analyses, and a reasonable explanation was provided with DFT calculations.