Electrospun fiber-based random lasers are environment-friendly flexible systems in which waveguiding/scattering processes provided by their structure with a broad distribution of diameters are essential elements to generate a suitable lasing mechanism. In this work, we prepared electrospun fibers with dual-size diameter distribution (above and below the critical value for waveguiding), allowing that both optical processes can be established in the polymer network. As a result, random laser emission was observed for the electrospun fibers presenting dual-size diameters with rhodamine 6G as the gain medium, characterizing the combination of waveguiding/scattering as an adequate condition for development of organic nanofibrous random lasers. Degradation assays were also performed in order to evaluate the prolonged use of such random laser systems.
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