Hierarchical structures in nature provide unique functions for living organisms that can inspire technology. Nanoscale hierarchical structured surfaces are essential to realize the dual functions of non-wetting and transparency for applications such as cover glasses and windows; however, these structures are challenging to fabricate. In this study, nano-hierarchical structured glass surfaces were fabricated using multi-step colloidal lithography and etching to obtain tunable morphology. Nanostructured surfaces of mono-pillar structures of diameter 120 and 350 nm and hierarchical-pillar structures of their combinations exhibited superhydrophobicity after perfluoropolyether coating. In particular, the hierarchical nanosurfaces showed excellent non-wetting properties with the apparent, advancing, and receding water contact angles exceeding 177° and contact angle hysteresis below 1°. Water bouncing behaviors - contact time, spreading diameter, and shape of the bouncing motion were also evaluated according to the Weber number to examine the robustness of superhydrophobicity. Hierarchical nanosurfaces showed larger spreading diameters than mono-nanosurfaces with 14 bounces, indicating minimal energy loss from friction, as can be explained by the effective slip length. Furthermore, the nano-hierarchical structures exhibited better transmittance for wide angles of incidence up to 70° than mono-nanostructures owing to their reduced scattering area and multi-periodicity.
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