Source-specific ecological risks and critical source identification of PPCPs in surface water: Comparing urban and rural areas

Abstract

To control the concentrations of pharmaceutical and personal care products (PPCPs) in the surface water of urban and rural areas, it is important to explore the spatial variation in source-specific ecological risks and identify critical sources. Here, we focused on 22 PPCPs found in the effluent from wastewater treatment plants and surface water in Tianjin, and source-specific risk was quantitatively apportioned combining positive matrix factorization with ecological risk assessment. Results showed that rural areas exhibited a more severe contamination level than urban areas. Medical wastewater (30.1 %) accounted for the highest proportion, while domestic sewage posed the greatest threat to aquatic ecosystems. The incidence of potential risks (RQ > 0.01) caused by domestic sewage in urban areas (88.9 %) was higher than that in rural areas (75.9 %). However, PPCP risks caused by farmland drainage, aquaculture, and livestock discharge were mainly distributed in rural areas. The critical source identified in the entire region was domestic sewage (weight, 0.36), and its weight (0.51) in urban areas was greater than that in rural areas (0.32). The impact of aquaculture (weight, 0.16) in rural areas was noteworthy. These findings may contribute to developing environmental management strategies in key areas to help alleviate PPCP contamination worldwide.

Keywords: Critical source identification; Pharmaceutical and personal care products; Positive matrix factorization; Source-specific ecological risks; Urban-rural areas.