1 School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Tianjin University, Tianjin 300072, China. xiaobinfan@tju.edu.cn.
2 Beijing Institute of Metrology, Beijing, 100029, China.
3 Faculty of Chemical Engineering, Kunming University of Science and Technology, The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming, 650500, China.
4 Institute of Shaoxing, Tianjin University, Zhejiang 312300, China.
5 Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China.
The high dielectric loss tangent value of black phosphorus nanosheets enables them to be selectively heated under microwave radiation to realize the in situ surface reaction of BP with Ni2+ to prepare thermodynamically unstable two-dimensional Ni2P.