Tuning Electrochemical Performance of Li-Rich Layered Cathode Materials with a Solid Phase Fusion Strategy

Xiangnan Li; Qibin Zhou; Shuaijia Yang; Ming Ge; Huishuang Zhang; Yanhong Yin; Shuting Yang

doi:10.1021/acs.langmuir.2c01230

Tuning Electrochemical Performance of Li-Rich Layered Cathode Materials with a Solid Phase Fusion Strategy

Langmuir. 2022 Sep 20;38(37):11219-11226. doi: 10.1021/acs.langmuir.2c01230. Epub 2022 Sep 5.

Authors

Xiangnan Li^{1

2

3}, Qibin Zhou^{1

2

3}, Shuaijia Yang¹, Ming Ge^{1

2

3}, Huishuang Zhang^{1

2

3}, Yanhong Yin^{1

2

3}, Shuting Yang^{1

2

3}

Affiliations

¹ School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China.
² National and Local Joint Engineering Laboratory of Motive Power and Key Materials, Xinxiang, Henan 453007, China.
³ Collaborative Innovation Center of Henan Province for Motive Power and Key Materials, Xinxiang, Henan 453007, China.

PMID: 36064317
DOI: 10.1021/acs.langmuir.2c01230

Abstract

Li-rich layered cathode materials (LRMs) have attracted extensive attention because of their high theoretical specific capacity. However, their practical application is limited by the severe depreciation of capacity and voltage during cycling. Herein, high electrical conductivity MoS₂ is constructed on Li_1.2Ni_0.2Mn_0.6O₂ (LLNM) surface through solid phase fusion technology (SFT). Extraordinarily, the MoS₂ modified layer lessens the interface side reaction and stabilizes the surface structure of LLNM. Meanwhile, the strong electron conductivity of MoS₂ speeds up electron transit at the surface. The results demonstrate that LLNM-M10 exhibits a remarkable electrochemical performance as it retains 183.3 mA h g^-1 at 1 C after 250 cycles. More crucially, the modified electrode exhibits an exceptional low-temperature performance of 120.3 mA h g^-1 at 0.1 C and -10 °C. Therefore, this presented strategy may provide a new method for further application of Li-rich layered cathode materials.