Recent advances in carbonaceous catalyst design for the in situ production of H2O2 via two-electron oxygen reduction

Abstract

The electrochemical oxygen reduction reaction has received increasing attention as a relatively green, safe and sustainable method for in situ hydrogen peroxide (H₂O₂) production. Recently, significant achievements have been made to explore carbon-based (noble metal-free) low-cost and efficient electrocatalysts for H₂O₂ electroproduction, which could potentially replace the traditional anthraquinone process. However, to realize industrial-scale implementation, a highly active and selective catalytic material is needed. In this review paper, we first expound on the oxygen reduction reaction (ORR) mechanism, which is the origin of in situ H₂O₂ production. Then, the recent progress in the development of modified carbon-based catalysts is reviewed and classified, corresponding to their physical or chemical modulation. Furthermore, an overview is provided of the available examples from pilot/large-scale applications. Finally, an outlook on the current challenges and future research prospects to transfer the lab-developed catalysts into pilot or industrial-scale reactors is briefly discussed.

Keywords: Advanced oxidation processes; Cathode; Electrocatalyst; Hydrogen peroxide; Oxygen reduction reaction.