Constructing robust polymer/two-dimensional Ti3C2TX solid-state electrolyte interphase via in-situ polymerization for high-capacity long-life and dendrite-free lithium metal anodes

Abstract

We constructed an artificial polymer/two-dimensional Ti₃C₂T_X (MXene) solid electrolyte interphase (SEI) on a Li metal surface via an in-situ polymerization strategy. The polymer layer provides excellent interface contact and outstanding adaptability for the volume expansion of Li metal, decreasing interface impedance. On the other hand, the two-dimensional MXene with a low Li nucleation energy barrier is beneficial for uniform Li deposition and restraint of interfacial side reactions. In this work, a dense and durable MXene-integrated SEI between the Li metal anode and solid-state electrolyte (SSE) interface is constructed to render the Li/SSE/Li cell to maintain a stable polarization voltage of approximately 50 mV at a capacity of 0.50 mAh cm^-2 for over 1000 h. It enables the Li/SSE/LiFePO₄ cell to deliver a capacity of 130.1 mAh g^-1 at 1C with a capacity retention of 91.4% after 900 cycles. Therefore, we believe that this facile in-situ polymerization method for constructing a layer of polymer/MXene SEI at the interface between Li metal anodes and SSE can promote the practical applications of Li metal batteries.

Keywords: Artificially protected layer; Lithium dendrite; Lithium metal anode; MXene; Solid electrolyte interphase.