The Study of Chemical and Thermal Influences of the Environment on the Degradation of Mechanical Properties of Carbon Composite with Epoxy Resin

Polymers (Basel). 2022 Aug 9;14(16):3245. doi: 10.3390/polym14163245.

Abstract

The present research deals with the investigation of the influence of aqueous solutions of chemical substances in combination with temperature on the change of material properties of polymer composites based on epoxy resins reinforced with carbon fibers. The aim of the research was to investigate and evaluate the impact of degradation processes due to the influence of chemical environments of different temperatures and time of their action on changes in the material properties and macrostructure of carbon composite with epoxy resin. The chemical and thermal influence of the environment on the experimental material was evaluated by monitoring changes in mechanical properties, glass transition temperature, and material surface macrostructure. The achieved results show different behavior of the experimental composite material in different environments, while it was demonstrated that the degradation effect of chemical and thermal influences on changes in material properties increase with increasing temperature. Among the investigated environments (NaCl, NaOH, and H2SO4), exposure to 10% NaOH, and 15% H2SO4 had the greatest degradation influence on the polymer composite, and exposure to 20% NaCl had the smallest influence, which is also confirmed by invisible changes in material surface macrostructure and decrease of tensile strength by about 20%. Exposure to 10% NaOH resulted in significant surface roughening of the epoxy resin, white deposit creation on the surface, and a decrease of tensile strength by 35%. Opposite that, exposure to 15% H2SO4 resulted in the highlighting of the fiber yarns of the carbon fiber fabric, yellowing of the surface, surface pore occurrence, and a decrease of tensile strength by 35%.

Keywords: carbon composite with epoxy resin; chemical and thermal influence; glass transition temperature; material surface macrostructure; mechanical properties.