Deep eutectic solvents (DES) have been widely studied for interesting solvent properties in resources utilization and green conversion of energy. Complex composition of DES and lack of recovery techniques restricts their further scale-up application. Exploring efficient recovery and regeneration methodology of DES in biorefinery could be beneficial for low-carbon circular bioeconomy. Recovery and regeneration of choline-polyol DES (choline chloride-ethylene glycol, ChCl-EG) after biomass pretreatment was studied using bipolar membrane electrodialysis (BMED) with ultrafiltration (UF). UF-BMED treatment worked based on the interception of macromolecular degradation products in pretreatment liquor and regional recovery of Ch+, Cl- with EG. Influence of major parameters on DES recovery performance was studied with emphasis. Maximum recovery ratio of DES reached 97.4% and minimum specific energy consumption of DES recovery approached 6.0 kW·h/kg. Cognition gained from this research revealed an efficient technique for DES recycling after biorefinery.
Keywords: Biorefinery; Deep eutectic solvent; Recovery; Regeneration.
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