The water hyacinth has been identified as a persistent threat to the pillars of sustainability, resulting in an increased demand for cost-effective mitigation measures. Existing control measures such as chemical and mechanical methods have proved ineffective and expensive, although their use in a biorefinery is deemed sustainable. The study focused on using the response surface methodology of Design-Expert to optimise process parameters, emphasising temperature and particle size, to improve the liquid fraction yield from the pyrolysis of water hyacinths. The experiment was conducted in the temperature range of 273.22 and 676.78 °C, with a particle size range of 380 and 2620 µm, and subjected to a heating rate of 30 °C/min and a nitrogen flow rate of 25 l/min. The results suggest that an increase in temperature and particle size led to a rise in the liquid fraction and a decrease in char. The liquid fraction increased from 24.36 wt.% at 273.22 °C to 48.45 wt.% at 575 °C and reduced to 25.56 wt.% at 626.78 °C. Char decreased from 58.21 to 33.84 wt.% at 626.78 °C. Given this, the quadratic model was found fit for optimisation. Statistical analysis of variance showed good agreement between actual data and the predicted model. This study argues that the valorisation of water hyacinths, if accompanied by policies and strategies, can trigger comprehensive socio-economic and environmental benefits by implementing optimum conditions to generate an improved liquid fraction that tends to influence its commercialisation. It is envisaged that the study's findings will inform policy discussions and formulation.
Keywords: Bio-oil; Biochar; Biomass; Biorefinery; Central composite design; Eichhornia crassipes.
© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.