Electrocatalytic water splitting is a promising and viable technology to produce clean, sustainable, and storable hydrogen as an energy carrier. However, to meet the ever-increasing global energy demand, it is imperative to develop high-performance non-precious metal-based electrocatalysts for the oxygen evolution reaction (OER), as the OER is considered the bottleneck for electrocatalytic water splitting. Spinels, in particular, are considered promising OER electrocatalysts due to their unique properties, precise structures, and compositions. Herein, the recent progress on the application of bimetallic-based spinels (AFe2 O4 , ACo2 O4 , and AMn2 O4 ; where A = Ni, Co, Cu, Mn, and Zn) as electrocatalysts for the OER is presented. The fundamental concepts of the OER are highlighted after which the family of spinels, their general formula, and classifications are introduced. This is followed by an overview of the various classifications of bimetallic-based spinels and their recent developments and applications as OER electrocatalysts, with special emphasis on enhancing strategies that have been formulated to improve the OER performance of these spinels. In conclusion, this review summarizes all studies mentioned therein and provides the challenges and future perspectives for bimetallic-based spinel OER electrocatalysts.
Keywords: electrocatalysts; hydrogen; oxygen evolution reaction; spinels; water splitting.
© 2022 The Authors. Small published by Wiley-VCH GmbH.