Multiplex heteroatoms doped carbon nano dots with enhanced catalytic reduction of ionic dyes and QR code security label for anti-spurious applications

Abstract

Herein, a simple hydrothermal approach was used to make multiplex heteroatoms doped carbon dots from Tinospora cordifolia miers plant extract. Their ability to the catalytic activity of dyes and anti-spurious applications was evaluated. The formation of NBCNDs and source of (T. cordifolia miers) study the optical properties, and functional groups are investigated using UV-Visible spectroscopy and FT-IR techniques. The synthesized NBCNDs structure and elemental compositions were examined via HR-TEM, XRD, and XPS, respectively. According to the HRTEM images, the average particle size of the NBCNDs was around 4.3± 1 nm, with d-spacing of 0.19 nm. The obtained NBCNDs were exposed under 395 nm UV light to emit bluish-green tuneable fluorescence with QY (quantum yield) of 23.7%. The prepared NBCNDs as a potential catalyst for the AYR and CV dye reduction process using freshly prepared NaBH₄, with determined rate constant values at 0.1220 and 0.1521 min^-1, respectively. Lastly, we constructed a quick response (QR) code security label for anti-spurious applications using stencil techniques. The "confidential info" was encrypted using a QR code digital system, and the decryption was read using a smartphone under 365 nm light irradiation.

Keywords: Anti-spurious; Carbon nanodots; Encryption; Quantum yield.